Study of the performance of a trickle bed reactor applied to oil hydrodesulfurization process
DOI:
https://doi.org/10.14808/sci.plena.2016.054203Keywords:
trickle bed reactor, hydrodesulfurization, heterogeneous modelAbstract
A heterogeneous reactor model in one-dimensional transient was developed to simulate a trickle bed reactor (TBR) applied to hydrodesulfurization (HDS) of oil. The model incorporates the resistance to mass transfer in gas-liquid and liquid-solid interfaces and an expression of the reaction rate based kinetic model of Langmuir-Hinshelwood type. Through parameter estimation, the model was fitted based on experimental data from a pilot-scale reactor and then validated under different experimental conditions. Finally, it were studied both H2S inhibiting effect and the effect of operating conditions on the HDS conversion, such as pressure, temperature, and liquid hourly space velocity (LHSV).
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